Coordination chemistry of P-rich phosphanes and silylphosphanes. XXIV. [1]formation and structure of [mu-(1,2 : 2-eta-(Bu2P)-Bu-t-P){Mo(CO)(2)cp '}(2)]

Authors
Krautscheid, H Matern, E Olkowska-Oetzel, J Pikies, J Fritz, G
Citation
H. Krautscheid et al., Coordination chemistry of P-rich phosphanes and silylphosphanes. XXIV. [1]formation and structure of [mu-(1,2 : 2-eta-(Bu2P)-Bu-t-P){Mo(CO)(2)cp '}(2)], Z ANORG A C, 627(7), 2001, pp. 1505-1507
Citations number
10
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
627
Issue
7
Year of publication
2001
Pages
1505 - 1507
Database
ISI
SICI code
0044-2313(200107)627:7<1505:CCOPPA>2.0.ZU;2-N
Abstract
[cp'Mo(CO)(2)](2) (cp' = (C5H4Bu)-Bu-t) reacts with (Bu2P)-Bu-t-P=P(Me)Bu-t (2) to yield the compound [mu-(1,2:2 eta-(Bu2P)-Bu-t-P) (Mo(CO)(2)cp'}(2)], which crystallizes in the space group P2(1)2(1)2(1) With a=1202.42(7), b=1 552.48(8), and c=1765.3(1) pm.