Synthesis and characterization of the Lewis acid-base complexes SbCl5 center dot LB (LB = ICN, BrCN, ClCN, (1)/(2) (CN2), NH2CN, pyridine) - a combined theoretical and experimental investigation. The crystal structures of SbCl5 center dot NCCl and SbCl5 center dot NCCN center dot SbCl5
Tm. Klapotke et al., Synthesis and characterization of the Lewis acid-base complexes SbCl5 center dot LB (LB = ICN, BrCN, ClCN, (1)/(2) (CN2), NH2CN, pyridine) - a combined theoretical and experimental investigation. The crystal structures of SbCl5 center dot NCCl and SbCl5 center dot NCCN center dot SbCl5, Z ANORG A C, 627(7), 2001, pp. 1582-1588
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
The Lewis acid-base complexes SbCl5. LB (LB = ICN, BrCN, ClCN, 1/2(CN)(2),
NH2CN, pyridine) were prepared. The products formed were characterized by R
aman and NMR spectroscopy. Density functional theory (B3LYP) was applied to
calculate structural and vibrational data. Vibrational assignments of the
normal modes for these Lewis acid-base adducts was made on the basis of the
ir Raman spectra in comparison with computational results. The stability of
the complexes was investigated by calculating the bond dissociation enthal
py. SbCl5. NCCl and SbCl5. NCCN . SbCl5- were characterized by X-ray struct
ural analysis. NBO analyses were performed on the crystallographic data.