Iron complexes of the N(CH2CH2S)(3)(3-)(NS3) ligand with isocyanide co-ligands.

Authors
Cooper, L Davies, SC Dilworth, JR Hughes, DL Konkol, M Richards, RL Sanders, JR Sobota, P
Citation
L. Cooper et al., Iron complexes of the N(CH2CH2S)(3)(3-)(NS3) ligand with isocyanide co-ligands., CAN J CHEM, 79(5), 2001, pp. 490-494
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
79
Issue
5
Year of publication
2001
Pages
490 - 494
Database
ISI
SICI code
0008-4042(200105)79:5<490:ICOTNL>2.0.ZU;2-B
Abstract
The complexes NEt4[Fe(NS3)(CNR)] (1), [Fe{Fe(NS3)(CNR)}(2)-S,S'] (2), [Co{F e(NS3)(CNMe)}(2)-S,S' ] (3), and [Ni{Fe(NS3)(CNMe)}(2)-S,S'] (4) (R = Me, t -Bu, or C6H11(Cy)) have been prepared and the X-ray crystal structures of N Et4[Fe(NS3)(CNMe)] (1a) and [Fe{Fe(NS3)(CNCy)}(2)-S,S'] (2c) have been dete rmined. Mossbauer and IR spectroscopic data and room temperature magnetic m oments for these complexes are reported.