Study of the hydroformylation of 2,5-dihydrofuran catalyzed by rhodium diphosphine complexes

Authors
del Rio, I van Leeuwen, PWNM Claver, C
Citation
I. Del Rio et al., Study of the hydroformylation of 2,5-dihydrofuran catalyzed by rhodium diphosphine complexes, CAN J CHEM, 79(5), 2001, pp. 560-565
Citations number
47
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
79
Issue
5
Year of publication
2001
Pages
560 - 565
Database
ISI
SICI code
0008-4042(200105)79:5<560:SOTHO2>2.0.ZU;2-N
Abstract
Rhodium diphosphine systems, including chiral ones, were used as catalyst p recursors for the hydroformylation of 2,5-dihydrofuran. The effect of the r eaction conditions and the bite angle on the activity and selectivity of th e reaction were studied. The solution structures of the species present hav e been investigated spectroscopically through HP-NMR experiments during the hydroformylation reaction.