Electron spectroscopies play an essential role in the experimental characte
rization of the electronic structure of solids. After a short description o
f the techniques used, the paper reviews some of the most important results
obtained on purified single- and multi-wall carbon nanotubes, and intercal
ated nanotubes as well. An analysis of the occupied and unoccupied electron
states, and the plasmon structure of the nanotubes is provided. How this i
nformation can be used to characterize the samples is discussed. Whenever p
ossible, a comparison between nanotube data and those from graphite and C-6
0 fullerene is made, as to draw a coherent picture in the light of recent t
heories on the electronic properties of these C-sp(2) materials.