Synthesis and characterization of the heteroaromatic MF6- (M = As, Sb) salts of the 1,2,4-trithiolanylium dication [PhCSSC(Ph)S](2+)

Authors
Cameron, TS Decken, A Fang, M Passmore, J
Citation
Ts. Cameron et al., Synthesis and characterization of the heteroaromatic MF6- (M = As, Sb) salts of the 1,2,4-trithiolanylium dication [PhCSSC(Ph)S](2+), CHEM COMMUN, (15), 2001, pp. 1370-1371
Citations number
10
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
15
Year of publication
2001
Pages
1370 - 1371
Database
ISI
SICI code
1359-7345(2001):15<1370:SACOTH>2.0.ZU;2-6
Abstract
PhCSSC(Ph)S(MF6)(2) (M = As, Sb), (X-ray crystal structure, FT Raman, H-1, C-13 NMR and theoretical calculations) containing the first example of a di cationic 6 pi five-membered C-S heterocycle and sulfur were formed on dispr oportionation of PhCSSS(MF6) in liquid SO2 solution.