Spectroscopic characterization of catalytically active surface sites of a metallic oxide

Citation
H. Over et al., Spectroscopic characterization of catalytically active surface sites of a metallic oxide, CHEM P LETT, 342(5-6), 2001, pp. 467-472
Citations number
27
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
342
Issue
5-6
Year of publication
2001
Pages
467 - 472
Database
ISI
SICI code
0009-2614(20010720)342:5-6<467:SCOCAS>2.0.ZU;2-T
Abstract
High-resolution core-level photoelectron spectroscopy in combination with d ensity functional theory calculations was used to identify the spectroscopi c signatures of the catalytically active sites on the RuO2(110) surface, i. e., the coordinatively unsaturated Ru sites (cus-Ru) and the bridging oxyge n atoms. These assignments provide the necessary spectroscopic information for in situ studies of catalytical reactions over the RuO2(110) surface. (C ) 2001 Elsevier Science B.V. All rights reserved.