Self-assembly and X-ray structure determination of the novel 2-D layered organic-inorganic hybrid Pb-X compound: [PbX2(4,4 '-bipy)](n) (X=I,Br)

Citation
Yj. Shi et al., Self-assembly and X-ray structure determination of the novel 2-D layered organic-inorganic hybrid Pb-X compound: [PbX2(4,4 '-bipy)](n) (X=I,Br), CHEM LETT, (7), 2001, pp. 678-679
Citations number
23
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
7
Year of publication
2001
Pages
678 - 679
Database
ISI
SICI code
0366-7022(20010705):7<678:SAXSDO>2.0.ZU;2-U
Abstract
Two novel organic-inorganic hybrid compounds, [PbI2(4,4 ' -bipy)](n) (1) an d [PbBr2(4,4 ' -bipy)](n) (2), are synthesized by self-assembly. X-ray crys tallography analysis shows that the [PbI2], chains in 1 are linked by 4,4 ' -bipyridine to form a layer, via Pb-N bonding along the direction of the ' b' axis.