Reaction of 1-disilagermirene with benzaldehyde: An unexpected combinationof cycloaddition and insertion pathways

Authors
Lee, VY Ichinohe, M Sekiguchi, A
Citation
Vy. Lee et al., Reaction of 1-disilagermirene with benzaldehyde: An unexpected combinationof cycloaddition and insertion pathways, CHEM LETT, (7), 2001, pp. 728-729
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
7
Year of publication
2001
Pages
728 - 729
Database
ISI
SICI code
0366-7022(20010705):7<728:RO1WBA>2.0.ZU;2-U
Abstract
New strained bicyclic compounds were formed by the reaction of tetrakis[di- tert-butyl(methyl)silyl]-1 -disilagermirene 1 with benzaldehyde, involving cycloaddition following the rearrangement and insertion pathways. Reaction of 1 with PhCHO gave three different products: two mono-adducts 2, 3 and on e bis-adduct 4, depending on the ratio of the reagents and the reaction con ditions.