Volatile sulfur compounds produced enzymatically from Allium species have b
een identified by combined gas chromatography-mass spectrometry (GC-MS) and
the results obtained have been compared with those from HPLC-UV analysis (
with a diode-array detection, DAD). Analysis of the same onion sample by su
ccessive SPME-GC-MS or by solvent extraction then GCMS enabled us to identi
fy the true onion volatiles including lachrymatory factor and thiosulfinate
s. Conversely, for garlic samples HPLC analysis is more suitable because of
the substantial degradation of allicin (the main thiosulfinate in garlic)
during GC. An El mass spectrum of allicin obtained by GC-MS is reported for
the first time.