Dipole moment studies of molecular interactions of the type O-H...N

Authors
Subramanian, M Thenappan, T
Citation
M. Subramanian et T. Thenappan, Dipole moment studies of molecular interactions of the type O-H...N, I J PA PHYS, 39(7), 2001, pp. 417-420
Citations number
13
Categorie Soggetti
Physics
Journal title
INDIAN JOURNAL OF PURE & APPLIED PHYSICS
ISSN journal
00195596 → ACNP
Volume
39
Issue
7
Year of publication
2001
Pages
417 - 420
Database
ISI
SICI code
0019-5596(200107)39:7<417:DMSOMI>2.0.ZU;2-Y
Abstract
The dipole moments of 1:1 complexes of benzonitrile with benzyl alcohol(I) and O-cresol(II) in benzene and ethylene glycol(III) and Diethylene glycol( IV) in 1.4 Dioxan were determined at 308 K. The dipolar increments of these systems were computed from the bond angle data available from molecular or bital studies. Our results show that the polarization interaction dominates in all the complexes studied and no higher order complexation is indicated .