Synthesis and X-ray structure of the homobinuclear 2,2 '-biimidazole-bridged palladium(II) complex [{Pd(dppp)}(2)(mu-biim)](OTf)(2)

Authors
Maiboroda, A Rheinwald, G Lang, H
Citation
A. Maiboroda et al., Synthesis and X-ray structure of the homobinuclear 2,2 '-biimidazole-bridged palladium(II) complex [{Pd(dppp)}(2)(mu-biim)](OTf)(2), INORG CH C, 4(8), 2001, pp. 381-383
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
8
Year of publication
2001
Pages
381 - 383
Database
ISI
SICI code
1387-7003(200108)4:8<381:SAXSOT>2.0.ZU;2-6
Abstract
Homobinuclear [(Pd(dppp))(2)(mu -biim)1(OTf)(2) (4) (dppp=bis(diphenylphosp hino)propane. biim=2,2 \ -biimidazole, OTf = OSO2CF3) is accessible by the reaction of [Pd(dppp))(OTf)(2) (1) with H(2)biim (2) in the presence of an appropriate base. The structure of 4 was determined by X-ray crystallograph y. As a result thereof, the palladium atoms are located somewhat above and below the planar biim(2-) entity. (C) 2001 Elsevier Science B.V. All rights reserved.