Preparation of bis(hydrazine) complexes of iron(II)

Authors
Albertin, G Antoniutti, S Bordignon, E Chimisso, F
Citation
G. Albertin et al., Preparation of bis(hydrazine) complexes of iron(II), INORG CH C, 4(8), 2001, pp. 402-404
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
8
Year of publication
2001
Pages
402 - 404
Database
ISI
SICI code
1387-7003(200108)4:8<402:POBCOI>2.0.ZU;2-I
Abstract
Bis(hydrazine) complexes [Fe(RNHNH2)(2) (PPh(OEt)(2))(4)](BPh4)(2) (R = H, CH3) 1, 2 were prepared by allowing nitrile complexes [Fe(CH3CN)(2) (PPh(OE t)(2))(4)] (BPh4)(2) to react with hydrazine at 0 degreesC. The monohydrazi ne [Fe(NH2NH2)(CH3CN)(2)(P(OEt)(3))] (BPh4)(2) derivative was also obtained . Treatment of bis(hydrazine) 1. 2 with Pb(OAc)(4) led to the acetate compl ex [Fe(kappa (2)-O2CCH3) (PPh(OEt)(2))(4)]BPh4. (C) 2001 Elsevier Science B .V. All rights reserved.