A new cyanato-bridged polymeric complex [Cd-3 (NCO)(6)(NH2CH2C5H4N)(3)](n)with a zig-zag ladder shaped structure

Authors
Choudhury, CR Dey, SK Mondal, N Mitra, S Mahalli, SOG Malik, KMA
Citation
Cr. Choudhury et al., A new cyanato-bridged polymeric complex [Cd-3 (NCO)(6)(NH2CH2C5H4N)(3)](n)with a zig-zag ladder shaped structure, INORG CH C, 4(8), 2001, pp. 419-422
Citations number
17
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
8
Year of publication
2001
Pages
419 - 422
Database
ISI
SICI code
1387-7003(200108)4:8<419:ANCPC[>2.0.ZU;2-F
Abstract
A new cyanato-bridged polymeric complex [Cd-3(NCO)(6)(NH2CH2C5H4N)(3)](n) h as been synthesized and characterized by X-ray crystallography. There are t hree cadmium atoms. three chelated 2-(aminomethyl)pyridine and six end-on b ridging cyanato groups in the asymmetric unit. Each Cd atom is bonded to on e chelated C5H4NCH2NH2 base and four mu (2)-NCO groups in a distorted octah edral environment. Three such independent CdN6 octahedra share their bridgi ng edges to produce a zig-zag Ladder shaped polymeric network extending alo ng a. (C) 2001 Elsevier Science B.V. All rights reserved.