New polymeric structure of rhenium octahedral chalcocyanide complex: Ln(3+)-derived network with one-dimensional channels

Authors
Artemkina, SB Naumov, NG Virovets, AV Gromilov, SA Fenske, D Fedorov, VE
Citation
Sb. Artemkina et al., New polymeric structure of rhenium octahedral chalcocyanide complex: Ln(3+)-derived network with one-dimensional channels, INORG CH C, 4(8), 2001, pp. 423-426
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
4
Issue
8
Year of publication
2001
Pages
423 - 426
Database
ISI
SICI code
1387-7003(200108)4:8<423:NPSORO>2.0.ZU;2-A
Abstract
A novel cyanobridged coordination polymeric complex with octahedral rhenium cyanocluster anion [Re-6(mu (3) - Se)(8)(CN)(6)](4-) and Nd3+ cation has b een synthesised and structurally characterised. Its solid-state structure c ontains a channel-type polymeric network built from cluster anions and Nd3 through Re-CN-Nd-NC-Re interactions. For compound (H3O) {Nd(DMF)(3)(H2O)(3 )} [Re6Se8(CN)(6)]. space group R3c, unit cell parameters are: a = 32.514(5 ): c = 25.255(5) Angstrom. V = 23122(7) Angstrom (3), R-f = 0.0762. A pair of isomorphic complexes has been obtained with Ln = Pr3+, Ho3+ (C) 2001 Pub lished by Elsevier Science B.V.