Y. Bohari et al., Improvements of hydride generation for the speciation of arsenic in natural freshwater samples by HPLC-HG-AFS, J ANAL ATOM, 16(7), 2001, pp. 774-778
A new gas-liquid separator was used to improve the hydride generation step
of a hyphenated HPLC-HG-AFS system applied to arsenic speciation studies. O
ptimisation of the hydride generation atomic fluorescence detection with th
is new device produced by SpectraFrance led to a significant improvement in
performance. Absolute detection limits were as low as 5-7 pg As for the fo
ur arsenic species usually encountered in water samples: As(III), As(V), mo
nomethylarsonic acid (MMAA) and dimethylarsinic acid (DMAA). Using a 100 mu
l injection volume the concentration detection limits were in the range 0.0
5-0.07 ng ml(-1). The optimised procedure was applied to determine arsenic
speciation in a wide range of natural fresh water samples.