Physicochemical and analytical properties of surfactant-modified redox reagents of the diphenylamine series

The effect of the nature and concentration of aqueous solutions of surfacta nts (ions and micelles) on the spectrochemical, acid-base and redox propert ies of organic reagents of the diphenylamine series bearing different subst ituents in phenyl rings and at the bridging nitrogen atom was studied by po tentiometric titration and absorption and photoluminescence spectroscopy. T he surfactant micelle-reagent binding constants were determined, and the co rrelation between the binding constants and the above-mentioned properties was analyzed.