Densities, viscosities, and excess molar enthalpies of binary mixtures containing essential oils at (298.15 and 313.15) K. The (S)-(-)-limonene plus cineole, (S)-(-)-limonene plus linalool, and cineole plus linalool systems

Citation
F. Comelli et al., Densities, viscosities, and excess molar enthalpies of binary mixtures containing essential oils at (298.15 and 313.15) K. The (S)-(-)-limonene plus cineole, (S)-(-)-limonene plus linalool, and cineole plus linalool systems, J CHEM EN D, 46(4), 2001, pp. 868-872
Citations number
18
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
46
Issue
4
Year of publication
2001
Pages
868 - 872
Database
ISI
SICI code
0021-9568(200107/08)46:4<868:DVAEME>2.0.ZU;2-O
Abstract
Densities, rho, viscosities, eta, and excess molar enthalpies, H-m(E), of b inary mixtures containing (S)-(-)limonene [(-)-1-methyl-4-(1-methylethenyl) cyclohexene] + 1,8-cineole(1,3,3-trimethyl-2-oxabicyclo [2,2,2]octane), (S) -(-)-limonene + linalool (3,7-dimethyl-1,6-octadien-3-ol), and cineole + li nalool were determined at (298.15 and 313.15)K and at atmospheric pressure using a digital density meter, a Schott measuring system, and a flow microc alorimeter, respectively. The excess molar volumes, V-m(E), the viscosity d eviations, Delta eta, and the H-m(E)'s were calculated from experimental me asurements. Results were fitted to the Redlich-Kister polynomial to obtain the adjustable parameters and standard deviations. Results were also qualit atively explained in terms of molecular interactions.