Densities, viscosities, and excess molar enthalpies of binary mixtures containing essential oils at (298.15 and 313.15) K. The (S)-(-)-limonene plus cineole, (S)-(-)-limonene plus linalool, and cineole plus linalool systems
F. Comelli et al., Densities, viscosities, and excess molar enthalpies of binary mixtures containing essential oils at (298.15 and 313.15) K. The (S)-(-)-limonene plus cineole, (S)-(-)-limonene plus linalool, and cineole plus linalool systems, J CHEM EN D, 46(4), 2001, pp. 868-872
Densities, rho, viscosities, eta, and excess molar enthalpies, H-m(E), of b
inary mixtures containing (S)-(-)limonene [(-)-1-methyl-4-(1-methylethenyl)
cyclohexene] + 1,8-cineole(1,3,3-trimethyl-2-oxabicyclo [2,2,2]octane), (S)
-(-)-limonene + linalool (3,7-dimethyl-1,6-octadien-3-ol), and cineole + li
nalool were determined at (298.15 and 313.15)K and at atmospheric pressure
using a digital density meter, a Schott measuring system, and a flow microc
alorimeter, respectively. The excess molar volumes, V-m(E), the viscosity d
eviations, Delta eta, and the H-m(E)'s were calculated from experimental me
asurements. Results were fitted to the Redlich-Kister polynomial to obtain
the adjustable parameters and standard deviations. Results were also qualit
atively explained in terms of molecular interactions.