Excess molar volumes and viscosities for binary mixtures of 2-propoxyethanol and of 2-isopropoxyethanol with propylamine and dipropylamine at (298.15, 308.15, and 318.15) K

Citation
A. Pal et Rk. Bhardwaj, Excess molar volumes and viscosities for binary mixtures of 2-propoxyethanol and of 2-isopropoxyethanol with propylamine and dipropylamine at (298.15, 308.15, and 318.15) K, J CHEM EN D, 46(4), 2001, pp. 933-938
Citations number
29
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
46
Issue
4
Year of publication
2001
Pages
933 - 938
Database
ISI
SICI code
0021-9568(200107/08)46:4<933:EMVAVF>2.0.ZU;2-5
Abstract
Excess molar volumes V-m(E) and viscosities eta have been measured as a fun ction of composition for the binary mixtures of 2-propoxyethanol and of 2-i sopropoxyethanol with propylamine and dipropylamine at (298.15, 308.15, and 318.15) K. From the experimental data, the deviation in the viscosity eta from Sigmax(i) In eta (i) has been calculated at various temperatures. The excess molar volumes are negative whereas the deviation in the viscosities is positive for all investigated systems over the whole composition range. These results suggest that the stronger hydrogen bonds between unlike molec ules reduce the volume of the solution and make the solution high viscosity . A Redlich-Kister type equation was applied to fit the excess volumes and viscosity deviations, and McAllister's three-body and four-body interaction models were also used to correlate the kinematic viscosities.