Property changes of mixing for the 1-butanol plus methanol plus 2-methoxy-2-methylbutane system at 298.15 K and atmospheric pressure

Citation
A. Arce et al., Property changes of mixing for the 1-butanol plus methanol plus 2-methoxy-2-methylbutane system at 298.15 K and atmospheric pressure, J CHEM EN D, 46(4), 2001, pp. 962-966
Citations number
16
Categorie Soggetti
Chemistry,"Chemical Engineering
Journal title
JOURNAL OF CHEMICAL AND ENGINEERING DATA
ISSN journal
00219568 → ACNP
Volume
46
Issue
4
Year of publication
2001
Pages
962 - 966
Database
ISI
SICI code
0021-9568(200107/08)46:4<962:PCOMFT>2.0.ZU;2-Z
Abstract
Densities, refractive indices, and speeds of sound at 298.15 K and atmosphe ric pressure for the l-butanol + methanol + 2-methoxy-2-methylbutane ternar y system have been measured. Excess molar volumes, molar refraction, and is entropic compressibility changes of mixing were determined from experimenta l measurements. The results were fitted to the Redlich-Kister equation to o btain the coefficients. These property changes were also predicted using se veral empirical equations from the values of their constituent binary subsy stems, and the best results were obtained with the Kohler equation.