Reactions of pyrylium salts with nucleophiles. Part 26. The reaction with the cyanide anion revisited

Citation
C. Uncuta et al., Reactions of pyrylium salts with nucleophiles. Part 26. The reaction with the cyanide anion revisited, J CHEM R-S, (5), 2001, pp. 170-171
Citations number
6
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF CHEMICAL RESEARCH-S
ISSN journal
03082342 → ACNP
Issue
5
Year of publication
2001
Pages
170 - 171
Database
ISI
SICI code
0308-2342(200105):5<170:ROPSWN>2.0.ZU;2-N
Abstract
Reaction mechanisms are provided for the formation of diastereomeric 2,4-di alkyl-6-oxo-2,4-heptadienonitriles (including minor diastereoisomers observ ed for the first time) from 2,4,6-trialkylpyrylium salts and aqueous sodium cyanide.