This paper deals with the development of a new process for the deposition o
f thermal barrier coatings (TBC) based on chemical vapor deposition. (CVD).
The research program started in September 1998 under a BRITE/Euram III pro
ject. The CVD process involves the evaporation of zirconium zirconium and y
ttrium starting from metal-organic precursors and their reaction with oxyge
n in a hot wall reactor in order to deposit TBC layers. The influence of di
fferent deposition parameters such as evaporation temperature, pressure, an
d substrate temperature an structure, deposition rate, and process yield ar
e described The characterization of different precursors behavior is also d
escribed. Preliminary results, obtained with optimized conditions, have sho
wn ZrO2-Y2O3 columnar layers with deposition rates of interest from an indu
strial point of view.