HIGHLY STEREOSELECTIVE PREPARATION OF ALPHA-GLUCOSIDES UTILIZING ANOMERIZATION REACTION WITH MGBR2-CENTER-DOT-OET2 AND A CATALYTIC AMOUNT OF TITANIUM(IV)TETRAHALIDES

Authors
MUKAIYAMA T TAKEUCHI K UCHIRO H
Citation
T. Mukaiyama et al., HIGHLY STEREOSELECTIVE PREPARATION OF ALPHA-GLUCOSIDES UTILIZING ANOMERIZATION REACTION WITH MGBR2-CENTER-DOT-OET2 AND A CATALYTIC AMOUNT OF TITANIUM(IV)TETRAHALIDES, Chemistry Letters, (7), 1997, pp. 625-626
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
7
Year of publication
1997
Pages
625 - 626
Database
ISI
SICI code
0366-7022(1997):7<625:HSPOAU>2.0.ZU;2-U
Abstract
The anomerization reactions of several beta-D-glucopyranosides proceed smoothly in the coexistence of MgBr2 . OEt2 and a catalytic amount of titanium(IV)halides to afford the corresponding alpha-D-glucopyranosi des. The desired alkyl alpha-glucosides and alpha-anomer of disacchari des such as Glc alpha 1-6Glc were obtained in high yields with high st ereoselectivities.