Poly(10,11-epoxyundecanoic acid), poly(5,6-epoxyhexanoic acid), and some of their derivatives

Authors
Vogl, O Kiliman, LB
Citation
O. Vogl et Lb. Kiliman, Poly(10,11-epoxyundecanoic acid), poly(5,6-epoxyhexanoic acid), and some of their derivatives, J MACR S PU, 38(2), 2001, pp. 123-135
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY
ISSN journal
10601325 → ACNP
Volume
38
Issue
2
Year of publication
2001
Pages
123 - 135
Database
ISI
SICI code
1060-1325(2001)38:2<123:PAPAAS>2.0.ZU;2-P
Abstract
The two most accessible omega -undecanoates, 5-hexenoate and 10-undecenoate have been epoxidized to the corresponding 5,6-epoxyhexanoate and improved polymerization techniques have allowed a large-scale production of the poly mers. Quantitative hydrolysis made the polymeric acids available for their transformation with diimidazolylcarbonyl to the highly reactive polymeric c arboxylic acids imidazolids.