Using pseudopotential density functional theory within the local-density ap
proximation, we calculate the ideal shear strengths of W for slip on {110},
{112} and {123} planes allowing for complete structural relaxation orthogo
nal to the applied shear. The strengths in the weak direction on all planes
are found to very nearly equal (about 18 GPa, or 11% of the shear modulus
G). Moreover, the shear instability occurs at approximately the same applie
d shear strain (17-18%). This unusual isotropy is explained in terms of the
atomic configuration of high-energy saddle points reached during shear. An
alysis of these saddle points may also offer a simple explanation for the p
revalence of the pencil glide of dislocation on planes containing a < 111 >
direction in bcc metals. Finally, we calculate the ideal cleavage strength
of W on {100} and compare our calculated ideal shear and cleavage strength
s with experimental nanoindentation and whisker measurements. All these res
ults can be rather simply understood using a Frenkel-Orowan crystallographi
c mode.