In situ scanning tunneling microscopy (STM) observations of initial growth
processes of GaN by molecular-beam epitaxy reveal important differences bet
ween growth on vicinal versus flat SiC(0001) substrates. Based on stop-grow
th STM studies, we explain why there are orders of magnitude reductions in
the density of threading screw dislocations in the vicinal films. It is sho
wn that on vicinal surfaces, three-dimensional (3D) islands develop into a
characteristic shape. The islands coalesce much sooner than on flat surface
s. Consequently, fewer defects are created at their boundaries.