Polarized laser selective excitation and Zeeman infrared absorption of C-4v and C-3v symmetry centers in Eu3+-doped CaF2, SrF2, and BaF2 crystals - art. no. 035102
Laser selective excitation and Zeeman infrared-absorption spectroscopy have
been employed to study Eu3+ centers in CaF2, SrF2, and BaF2 crystals. At l
ow dopant concentrations (less than or equal to0.1 mol%), the dominant cent
er for both CaF2 and SrF2 crystals is the well-established C-4v(F-) center
that consists of a Eu3+-F- dipole oriented along the [100] crystallographic
directions. The dominant center for BaF2:Eu3+ and a second center in SrF2:
Eu3+ has C-3v symmetry with the charge compensating F- ion residing in an i
nterstitial position along the [111] directions. In all three crystals, non
locally charge-compensated cubic symmetry centers are also present. Zeeman
measurements of the infrared absorption transitions to the Eu3+7F6 multiple
t reveal interesting nonlinear Zeeman splittings as a function of the appli
ed magnetic field. Crystal-and magnetic-field analyses of the C-4v(F-) and
C-3v(F-) centers give crystal-field parameters that are in agreement with t
hose of other rare-earth ions and that well account for the measured Zeeman
splittings.