Exciton characteristics of GaTe single crystals grown by vapor-phase transp
ort were studied by,optical measurements. A hydrogenlike exciton series up
to n=4 was clearly observed in the absorption spectra at 2 K. In the n=1 ex
citon energy region three types of exciton lines were found. By analyzing m
icrophotoluminescence and micro-Raman-scattering spectra on the basis of gr
oup theory, it was clarified that these exciton lines are not due to differ
ent polytypes but to intrinsic exciton states. Furthermore, optical-absorpt
ion spectra in a magnetic field at 4.2 K were measured. In the Voigt config
uration, one and two components for E parallel tob and E perpendicular tob
polarizations, respectively, were observed in the n = 1 and 2 exciton lines
. These magnetic-field dependencies cannot be interpreted on the basis of t
he previously proposed L-S coupling regime. The electronic band structure o
f GaTe was studied by the ab initio tight-binding linear muffin-tin orbital
s method. It was found that GaTe is a direct-gap semiconductor and that the
band edge is located at an M point of the Brillouin zone. From a compariso
n df exciton absorption spectra and the calculated band structure, the exis
tence of the three types of excitons was interpreted from the viewpoint of
j-j coupling. Our model calculation Was also able to explain the Zeeman spl
itting and the diamagnetic shift of the exciton peak energies.