We studied the photoluminescence (PL) spectrum resulting of the indirect re
combination of barrier electrons and the two-dimensional hole gas (2DHG) th
at is excited in a structure of mixed type-I-type-II GaAs/AIAs quantum well
s. This structure consists of alternating narrow and wide GaAs quantum well
s (QW), and is distinguished by a staggered conduction-band alignment that
leads to a fast electron transfer from the narrow to the wide QW's and a ve
ry slow hole transfer. Consequently, a 2DHG and a two-dimensional electron
gas (2DEG) are formed in the narrow and wide QW's, respectively. Their dens
ity is controlled by the photoexcitation intensity and is experimentally de
termined by fitting the band shape of the wide-well direct-recombination PL
spectra (in the range of 10(10)<n(e)<5 x 10(11) cm(-2)). A small fraction
of the electrons recombine radiatively with the 2DHG while they are in the
lowest X subband of the AlAs barrier, and the resulting spectrum is investi
gated at T=2 K and for various excitation intensities. The indirect transit
ions consist of a no-phonon band and momentum conserving (zone-edge) phonon
sidebands. All these bands are blueshifted with increasing photoexcitation
intensity. This shift is well explained by calculating the lowest X subban
d energy in the electrostatic potential, generated by the separate 2DEG and
2DHG charges as a function of their density.