We present the first x-ray spectroscopic measurements of the ionization bal
ance in inertial confinement fusion hohlraums supported by 4 omega Thomson
scattering diagnostics. The experimental data show agreement with non-LTE r
adiation-hydrodynamic calculations of the averaged Au charge state and elec
tron temperatures. These findings are consistent with the successful integr
ated modeling of the hohlraum radiation fields. Comparisons with detailed s
ynthetic spectra calculations show that the experimental ionization distrib
ution is slightly shifted indicating nonsteady state kinetics.