FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY APROTIC SUPERACIDS .6.EFFECTIVE REGIOSELECTIVE MONOFORMYLATION OF ADAMANTANE IN THE PRESENCE OF A HYDRIDE ION DONOR

Authors
AKHREM IS CHURILOVA IM VITT SV ORLINKOV AV VOLPIN ME
Citation
Is. Akhrem et al., FUNCTIONALIZATION OF SATURATED-HYDROCARBONS BY APROTIC SUPERACIDS .6.EFFECTIVE REGIOSELECTIVE MONOFORMYLATION OF ADAMANTANE IN THE PRESENCE OF A HYDRIDE ION DONOR, Russian chemical bulletin, 46(3), 1997, pp. 491-495
Citations number
19
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
3
Year of publication
1997
Pages
491 - 495
Database
ISI
SICI code
1066-5285(1997)46:3<491:FOSBAS>2.0.ZU;2-B
Abstract
The inefficient formylation of adamantane by CO initiated by superacid systems based on polyhalomethanes and aluminum halides becomes select ive in the presence of methylcyclopentane and affords 1-adamantanecarb aldehyde in an almost quantitative yield under mild conditions.