SYNTHESIS OF NEUTRAL TRINUCLEAR AND TETRANUCLEAR ORGANOMETALLIC CLUSTERS OF GROUP-VIII TRANSITION-METALS

Authors
KUDINOV AR MURATOV DV RYBINSKAYA MI PETROVSKII PV
Citation
Ar. Kudinov et al., SYNTHESIS OF NEUTRAL TRINUCLEAR AND TETRANUCLEAR ORGANOMETALLIC CLUSTERS OF GROUP-VIII TRANSITION-METALS, Russian chemical bulletin, 46(3), 1997, pp. 559-567
Citations number
20
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
46
Issue
3
Year of publication
1997
Pages
559 - 567
Database
ISI
SICI code
1066-5285(1997)46:3<559:SONTAT>2.0.ZU;2-N
Abstract
A number of earlier unknown tri- and tetranuclear organometallic clust ers of group VIII transition metals was synthesized by the addition of coordinatively unsaturated species to a single metal-metal bond. A nu mber of novel heteronuclear clusters, CpCp2'RhM2(mu-Co)(3)(mu(3)-CO), (Cp' = Cp, Cp; M-2 = Ru-2, Fe-2, RuFe); Cp2Cp*Rh2M2(mu(3)-CO)(3) (M = Ru, Fe); Cp3CpRh3M(mu(3)-CO)(2)(mu(3)-rl) (M = Ru, Fe); Cp2Cp*2Rh2Co 2(mu(3)-CO)(2), etc., was obtained.