The application of the technique of atom probe tomography to the atomic sca
le characterization of interfaces and surface films is described. The three
-dimensional atom probe determines the coordinates and elemental identities
of the atoms in a small volume of a sample with near-atomic precision. The
types of analyses that may be performed on interfaces are demonstrated by
examples taken from a variety of materials, including neutron-irradiated pr
essure-vessel steel welds, superalloys, surface films and model alloys. Pub
lished in 2001 by John Wiley & Sons, Ltd.