Preparation and characterization of [Fe(III)W11O39FH4](6-), a new member of the 1 : 11 heteropolyoxofluorotungstate anions

Authors
Wasfi, SH Johnson, WL McMasters, S
Citation
Sh. Wasfi et al., Preparation and characterization of [Fe(III)W11O39FH4](6-), a new member of the 1 : 11 heteropolyoxofluorotungstate anions, SYN REAC IN, 31(3), 2001, pp. 391-403
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
31
Issue
3
Year of publication
2001
Pages
391 - 403
Database
ISI
SICI code
0094-5714(200103)31:3<391:PACO[A>2.0.ZU;2-A
Abstract
The X-ray powder pattern of crystalline (NH4)(6)[Fe(III) W11O39FH4]. 7H(2)O shows that the anion has a structure similar to the distorted Keggin struc ture. Supporting evidence from elemental analyses, infrared spectroscopy, u ltraviolet-visible spectroscopy, cyclic voltammetry, and fast atom bombardm ent mass spectroscopy are presented. The Fe(III) ion is believed to occupy the octahedral site vacated by the missing W(VI) ion of the Keggin structur e.