Synthesis and complexation of a new soluble multidentate diaminoglyoxime derivative

Authors
Gurol, I Ahsen, V
Citation
I. Gurol et V. Ahsen, Synthesis and complexation of a new soluble multidentate diaminoglyoxime derivative, SYN REAC IN, 31(1), 2001, pp. 127-138
Citations number
30
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
31
Issue
1
Year of publication
2001
Pages
127 - 138
Database
ISI
SICI code
0094-5714(200101)31:1<127:SACOAN>2.0.ZU;2-K
Abstract
A new vic-dioxime, 12,13-bis(hydroxyimino)-11,14-diazatetracosane (H2L), ha s been prepared from decylamine and (E,E)-dichloroglyoxime. Monomeric Ni(II ) [(E,E) and (E,Z)], Co(II) and Pd(II) complexes are obtained with a metal- ligand ratio of 1:2. A dimetric complex with UO2 and polymeric Cu(II), Co(I I), Pd(II), and (E,Z)-Ni(II) complexes were prepared. All monomeric complex es are very soluble in common organic solvents, but the dimeric uranyl comp lex and polymeric complexes are not soluble. H-1 and C-13 NMR, IR, MS, and UV-vis data are presented.