Aza-Diels-Alder reactions of 2-(phenylthio)-1,3-butadiene with simple iminium salts

Citation
Ssp. Chou et Cc. Hung, Aza-Diels-Alder reactions of 2-(phenylthio)-1,3-butadiene with simple iminium salts, SYN COMMUN, 31(7), 2001, pp. 1097-1104
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
7
Year of publication
2001
Pages
1097 - 1104
Database
ISI
SICI code
0039-7911(2001)31:7<1097:ARO2WS>2.0.ZU;2-W
Abstract
The titled compound 2 was readily prepared by thermal desulfonylation of 3- (phenylthio)-3-sulfolene (1). The aza-Diels-Alder reactions of 2 with some simple iminium salts gave the cyclized products 3-7 in good yield with comp lete control of regiochemistry.