Chemoselective oxidation of 1,4-dihydropyridines with [NO+. crown.H(NO3)(2)(-)]

Authors
Zolfigol, MA Zebarjadian, MH Sadegh, MM Mohammadpoor-Baltork, I Memarian, HR Shamsipur, M
Citation
Ma. Zolfigol et al., Chemoselective oxidation of 1,4-dihydropyridines with [NO+. crown.H(NO3)(2)(-)], SYN COMMUN, 31(6), 2001, pp. 929-934
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
6
Year of publication
2001
Pages
929 - 934
Database
ISI
SICI code
0039-7911(2001)31:6<929:COO1W[>2.0.ZU;2-Z
Abstract
An ionic complex has been obtained from N2O4 in the presence of the macrocy clic ether 18-crown-6. This crystalline compound was used as an effective o xidizing agent for the oxidation of dihydropyridines to their corresponding pyridine derivatives at room temperature with excellent yields.