Citation
Pj. Chenier et al., Synthesis and x-ray crystallography of chiral tropocoronands, SYN COMMUN, 31(4), 2001, pp. 487-503
Citations number
21
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911
→ ACNP
Volume
31
Issue
4
Year of publication
2001
Pages
487 - 503
Database
ISI
SICI code
0039-7911(2001)31:4<487:SAXCOC>2.0.ZU;2-J
Abstract
The synthesis of several chiral tropocoronands (6 and 7) has been accomplis
hed. These compounds have been shown to complex with various metals. Tropoc
oronands that have been synthesized include H-2(TC-3,cyhex) through H2(TC-G
,cyhex) (6) and H-2(TC-3,diphen) through H-2(TC-6,diphen) (7). The route is
short and the tropocoronands are easily purified by chromatography or recr
ystallization. Two other groups have been incorporated into tropocoronands,
H-2(TC-3,binap) (9) and H-2(TC-6,pent) (10).