The high stereoselective synthesis of beta-alkynyl-enol phosphates

Citation
Yx. Ding et Xg. Huang, The high stereoselective synthesis of beta-alkynyl-enol phosphates, SYN COMMUN, 31(3), 2001, pp. 449-454
Citations number
12
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
31
Issue
3
Year of publication
2001
Pages
449 - 454
Database
ISI
SICI code
0039-7911(2001)31:3<449:THSSOB>2.0.ZU;2-5
Abstract
A high stereoselective synthesis for beta -allcynyl-enol phosphates from be ta -alkynyl ketone and dialkyl phosphite, via Atherton-Todd reaction, was r eported. NaH as base gave a nearly pure Z-isomer.