Ag. Santos et al., Rationalising diastereoselection in the dynamic kinetic resolution of alpha-haloacyl imidazolidinones: a theoretical approach, TETRAHEDRON, 57(30), 2001, pp. 6607-6614
A new model for the rationalisation of previously reported DKR results is p
resented. The proposed model is based both on experimental and molecular mo
delling results which indicate that selectivity arises from the interaction
between the leaving group and the stereodifferentiating substituent of the
chiral auxiliary. (C) 2001 Elsevier Science Ltd. All rights reserved.