Si(Li) lineshapes are generated using a model that incorporates Monte Carlo
simulation of the interactions of the incident photon, a very simple appro
ach to energy deposition by the primary (Auger and photo-) electrons, and a
n analytical approximation for diffusion of thermalized. secondary electron
s. The aim of the work is illustrative rather than quantitative. Interactio
ns in the metal contact produce various spectrum artefacts, and interaction
s in the silicon produce a low-energy shelf structure with well-defined ste
ps that have recently been observed experimentally but that are not mention
ed in previous Monte Carlo simulation work, although they are to be expecte
d on the basis of electron transport. Details of this structure are strongl
y influenced by pulse processing time in the electronic system. Artefacts a
rising from a silicon dead layer can enhance the escape peak intensity, and
can assist in estimating this layer's thickness. Inclusion in the simulati
on of Goto's model for secondary electron diffusion, incorporating reflecti
on at the metal-Si interface, results in a truncated low-energy shelf, whos
e threshold energy is determined by the reflection coefficient; its intensi
ty can also be predicted from an earlier, simple, analytical model that com
bines finite, primary, electron range effects with carrier losses in a regi
on of incomplete charge collection whose thickness is well defined. Copyrig
ht (C) 2001 John Wiley & Sons, Ltd.