Stratospheric ozone depletion was first reported in 1985. Early on, researc
hers identified polar stratospheric clouds (PSCs) as being important in che
mistry related to ozone depletion. PSCs exist as crystalline water-ice part
icles (type IT), and as crystalline (type Ia) or liquid (type Ib) particles
stable above the water-ice frost point. Uncertainty remains concerning the
composition and formation mechanism of the most common PSC, type Ia. Here,
we consider likely formation mechanisms for type Ia PSCs.