INFRARED-SPECTRA OF SOME URANIUM OXYFLUORIDE MOLECULES ISOLATED IN SOLID ARGON

Citation
Pf. Souter et L. Andrews, INFRARED-SPECTRA OF SOME URANIUM OXYFLUORIDE MOLECULES ISOLATED IN SOLID ARGON, Journal of molecular structure, 412(3), 1997, pp. 161-167
Citations number
26
Categorie Soggetti
Chemistry Physical
ISSN journal
00222860
Volume
412
Issue
3
Year of publication
1997
Pages
161 - 167
Database
ISI
SICI code
0022-2860(1997)412:3<161:IOSUOM>2.0.ZU;2-L
Abstract
Reaction of laser-ablated uranium with oxygen/fluorine mixtures or las er-ablated uranium dioxide ceramic with flourine produces the uranium oxyfluorides molecules UO2F2, UO2F and UOF4, which have been isolated in solid argon and identified by virtue of the effects of oxygen isoto pic substitution on their infrared spectra. (C) 1997 Elsevier Science B.V.