Mh. Huang et al., Effects of longitudinal wave on the resonance behavior of an electrode-separated piezoelectric sensor in liquids, ANALYT CHIM, 440(2), 2001, pp. 109-118
An electrode-separated piezoelectric sensor (ESPS) was constructed and its
operation in the liquid phase was characterized. When the surface of the se
parated-electrode reflects the weak longitudinal wave (LW) back to the surf
ace of the quartz disc where it was generated, the interaction of the refle
cted LW with the main thickness-shear wave of the quartz disc is a potentia
l error source. In this study, the influence of the LW effect on the respon
se of the ESPS was investigated by an impedance analysis method. It was sho
wn that all the impedance response parameters shift periodically as a funct
ion of the distance between the separated-electrode and the quartz crystal.
The LW effect depends markedly on the surface conditions, including the sh
ape, area, position, angle and roughness, of the separated-electrode. When
a rough, non-parallel or ball electrode was used, the influence of the LW c
ould be decreased greatly. The influence of the air/liquid interface on the
reflection of the LW was efficiently screened in the ESPS. (C) 2001 Elsevi
er Science B.V. All rights reserved.