The processes affecting salinization of precipitation, surface water,
vadose water and groundwater were studied in the Negev desert, Israel.
Observations spanning 18 years included the collection of rainfall at
three rain sampling stations, flood water at six flood stations, vado
se water from four coreholes penetrating chalk formations, and groundw
ater from 16 monitoring wells tapping the chalk aquitard, Dissolved ca
rbonate dust and evaporation of the falling raindrops result in Ca(HCO
3)(2) facies and increased ion concentration of the rainwater with res
pect to inland, more humid regions. The exposure of flood water to eva
poration during flood events is minimal. The observed Ca(HCO3)(2) faci
es and salt enrichment by a factor of three to five in the flood water
with respect to precipitation results primarily from interactions of
the flood water with the chalk and limestone bedrock, including ion ex
change on Na- and K-bearing minerals and the dissolution of calcite, g
ypsum and halite. The presence of these salts at and near land surface
results from the complete evaporation of rainwater in land surface de
pression storage areas following most rain events, Except for a small
portion moving through the low permeability chalk matrix, most of the
vadose water moves through preferential pathways and is typically not
exposed to evaporation. This dual movement of water accounts for the N
aCl facies of vadose water and the variable rates of isotopic depletio
n and salt dilution observed in the underlying heterogeneous groundwat
er in the saturated zone. Although the variable mixing with low-salini
ty, isotopically depleted water percolating from the fractures account
s for the depleted isotopic composition of the groundwater, its relati
vely low solute content cannot modify the groundwater NaCl facies. Con
sequently, only groundwater salinity in the chalk is reduced by the pr
eferentially flowing water, but the Ca(HCO3)(2) facies prevailing in t
he rainwater and flood water disappears, and the NaCl imprint from the
vadose zone prevails. (C) 1997 Elsevier Science B.V.