Gz. Wu, An alternative classical approach to the one-electron molecular orbital theory: the coset representation, CHEM P LETT, 343(3-4), 2001, pp. 339-344
Electronic populations and signs of the linear combination coefficients in
the one-electron molecular orbital (MO) theory are interpreted classically
as the analogs of action-angle variables. It is shown that in the coset rep
resentation algorithm there are action-angle variables that can substitute
for these quantities. Hence, one has an alternative algorithm to the one-el
ectron MO method, the classical coset approach. The extension to the multi-
site system is formulated which lays the foundation for possible applicatio
ns. The system of one electron in a linear lattice with random site energie
s is shown mimicking the Anderson localization. (C) 2001 Elsevier Science B
.V. All rights reserved.