A. Kamenev et Y. Gefen, DIFFERENCES BETWEEN STATISTICAL-MECHANICS AND THERMODYNAMICS ON THE MESOSCOPIC SCALE, Physical review. B, Condensed matter, 56(3), 1997, pp. 1025-1028
We present a systematic expansion in the ratio between the level spaci
ng and temperature and employ it to evaluate differences between stati
stical mechanics and thermodynamics in finite disordered systems. Thes
e differences are related to spectral correlations in those systems. T
hey are fairly robust and are suppressed at temperatures much higher t
han the level spacing.