C. Dallera et al., RESONANT SOFT-X-RAY INELASTIC-SCATTERING FROM GD IN THE GD3GA5O12 GARNET WITH EXCITATION ACROSS THE M-5 EDGE, Physical review. B, Condensed matter, 56(3), 1997, pp. 1279-1283
We present resonant soft-x-ray scattering measurements across the M-5
edge of Gd in Gd3Ga5O12. Below or near the Gd M-5 edge the scattering
is dominated by the elastic contribution, whereas the inelastic contri
bution becomes dominant above the edge. The theoretical cross section
is calculated in an ionic multiplet model, and the spectra are simulat
ed by including self-absorption and saturation effects. The calculatio
ns account for all the measured features. It is shown that the inelast
ic contributions to the spectra are due to 4f spin-flip excitations, b
ringing Gd to a lower spin state in the final state.