Rearrangement of a titanium alkoxide cluster upon substitution of the alkoxide groups by carboxylate ligands - Synthesis of [Ti6O4(OEt)(14)(OOCPh)(2)] from [Ti7O4(OEt)(20)]

Authors
Mijatovic, I Kickelbick, G Schubert, U
Citation
I. Mijatovic et al., Rearrangement of a titanium alkoxide cluster upon substitution of the alkoxide groups by carboxylate ligands - Synthesis of [Ti6O4(OEt)(14)(OOCPh)(2)] from [Ti7O4(OEt)(20)], EUR J INORG, (8), 2001, pp. 1933-1935
Citations number
20
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
8
Year of publication
2001
Pages
1933 - 1935
Database
ISI
SICI code
1434-1948(200108):8<1933:ROATAC>2.0.ZU;2-F
Abstract
Reaction of [Ti7O4(OEt)(20)] with benzoic acid results in the formation of the new cluster [Ti6O4(OEt)(14)(OOCPh)(2)] with concomitant rearrangement o f the cluster structure. The molecular structure of the new cluster was det ermined by single-crystal X-ray diffraction and can be represented by the e xtended formula [Ti-6(mu (4)-O)(2)(mu (2)-O)(2)(mu (2)-OEt)(6)(mu (2)-benzo ate)(2)(mu (1)-OEt)(8)].