The first transition metal complexes of 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene complexes of palladium(0), platinum(0), and silver(I)

Authors
Cerezo, S Cortes, J Lago, E Molins, E Moreno-Manas, M Parella, T Pleixats, R Torrejon, J Vallribera, A
Citation
S. Cerezo et al., The first transition metal complexes of 15-membered triolefinic macrocycles: (E,E,E)-1,6,11-tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-triene complexes of palladium(0), platinum(0), and silver(I), EUR J INORG, (8), 2001, pp. 1999-2006
Citations number
44
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
14341948 → ACNP
Issue
8
Year of publication
2001
Pages
1999 - 2006
Database
ISI
SICI code
1434-1948(200108):8<1999:TFTMCO>2.0.ZU;2-H
Abstract
(E,E,E)-1,6,1 1-Tris(arenesulfonyl)-1,6,11-triazacyclopentadeca-3,8,13-trie nes (1) form very stable complexes with Pd-0 and Pt-0, and moderately stabl e complexes with Ag-1. The three olefins in the macrocycle are responsible for the complexation. The X-ray structures of two complexes of Pdl and Pt-0 are presented; both complexes are planar trigonal.